2024 Photography Contest Winner
To Gel or Not to Gel: the Luminous Dilemma in the pH Alcove
Micrograph captured by Laser Scanning Confocal Microscopy (LSCM): the image displays a 1% wt solution of a Low Molecular Weight Gelator (LMWG) in 1:1 DMSO/H2O ratio, and containing a photoswitchable photoacid generator in a stoichiometric quantity. Upon irradiation with visible light (>400 nm) the photoswitch is reversibly forming a more acidic species, eventually altering the pH of the medium. When introduced to the LMWG and exposed to the Laser of the Confocal Microscopy (wavelength: 488 nm), the photoswitch generates the acid catalyst, subsequently lowering the pH of the solution. The chosen LMWG is sensitive to pH changes, self-assembling to form a gel when the pH drops below 5.5. Consequently, visible light irradiation leads to gel formation.
Notably, the activation of the photoswitch is temporary: eventually, after stopping the irradiation, the gel reverts back to a solution and process is entirely reversible.
The picture captures the moment when the fibers of the LMWG starts forming upon irradiation. The distinctive twisted ribbon-type nanofibrils of the LMWG can be clearly distinguished.